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 RONAR-SMITH®
LASER OPTICS & IR IMAGING
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Infrared Optical Material -
Si |
Infrared Optical Material -
Si
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CaF2
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GaAs |
Ge |MgF2|
Sapphire|ZnS | ZnSe| |
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Silicon
(Si) is grown by Czochralski pulling techniques (CZ)
and contains some that causes an absorption band at 9
microns. To avoid this, material can be prepared by
Float-Zone (FZ) process.Optical silicon is generally
lightly doped (5-40 ohm cm) for best transmission
above 10 microns, and doping is usaully boron (p-type)
and phosphorus (n-type). After doping silicon has a
further pass band: 30 to 100 microns which is
effective only in very high resistivity uncompensated
material.
CZ
Silicon is commonly used as substrate material for
infrared reflectors and windows in the 1.5-8 micron
region. The strong absorption band at 9 microns makes
it unsuitable for Co2 laser transmission applications,
but it is frequently used for laser mirrors because of
its high thermal conductivity and low density.
Application as window, lens in the 1.5-8 µm
region; Mirror for Co2 laser and spectrometer
applications.
Si
Optical grade
-
CZ,
P type doped with Boron, <111> or
<100>, Resistivity 5-40 ohm cm
-
FZ,
N type doped with phosphorus, <111>,
Resistivity > 50, preferably > 500 ohm cm,
the absorption at 9 microns is absent.
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| Optical
Properties |
| Transmission
Range |
1.2~8µm |
| Reflection
Loss, for two surfaces at 5µm |
46.2% |
| Reflection
Index |
See
below |
| Wavelength
(µm) |
Refractive
Index (n) |
Wavelength
(µm) |
Refractive
Index(n) |
| 1.357 |
/ |
5.500 |
3.4213 |
| 1.3951 |
3.4975 |
6.000 |
3.4202 |
| 1.6606 |
3.4929 |
6.500 |
3.4195 |
| 1.8131 |
3.4608 |
7.000 |
3.4189 |
| 2.1526 |
3.4476 |
7.500 |
3.4186 |
| 2.3254 |
3.443 |
8.000 |
3.4184 |
| 3.000 |
3.432 |
8.500 |
3.4182 |
| 3.500 |
3.4284 |
10.00 |
3.4179 |
| 4.000 |
3.4257 |
10.50 |
3.4178 |
| 4.500 |
3.4236 |
11.04 |
3.4176 |
| 5.000 |
3.4223 |
¡¡ |
¡¡ |
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| Physical
properties |
| Density |
2.33g/cm3 |
| Hardness,
Mohs |
7 |
| Dielectric
Constant for 9.37 x 109Hz |
13 |
| Melting
point, ¡ãC |
1414 |
| Thermal
Conductivity, W/m¡¤K at 313 K |
163 |
| Thermal
Expansion, 1/K at 293 K |
2.6x10-6 |
| Specific
Heat Capacity, J(kg¡¤¡ãC) |
712.8 |
| Bandgap,
eV |
1.1 |
| Knoop
Hardness, kg/mm2 |
1100 |
| Young's
Modulus, Gpa |
130.91 |
| Shear
Modulus, Gpa |
79.92 |
| Bulk
Modulus, Gpa |
101.97 |
| Debye
Temperature, K |
640 |
| Poisson's
Ratio |
0.28 |
| Chemical
properties |
| Solubility
in water |
None |
| Molecular
Weight |
28.09 |
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